Preparation and Characterization of CdS Intercalated Montmorillonite for Potentiometric Sensor Fabrication
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Published
Oct 28, 2021
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Abstract
In this investigation, CdS intercalated montmorillonite (CdS-MMT) was prepared by an in situ solid-solid reaction between Cd-montmorillonite (Cd-MMT) and Na2S as 1:1 molar ratio. The intercalated material was characterized by using X-ray diffraction (XRD), Fourier Transform Infrared Spectrophotometry (FT-IR) and Field Emission Scanning Electron Microscopy with Energy X-ray Dispersive (FE-SEM-EDX). According to XRD and FT-IR results, the basal spacing of interlayer space was significantly increased and also the intensity of Si-O-Si vibration stretching at wavenumber 1,000 cm-1 was decreased after treated by ion exchange. FE-SEM showed that clay crystal has flake like shape, resemble pillar structure. EDX quantitative data exhibited atomic (%) of Cd and S to be 7.64 and 5.23 % respectively. The ratio of sulfur and cadmium (S/Cd) was found 0.68 which closed to 1:1 molar ratio. The use of CdS-intercalated montmorillonite for electrochemical sensor is proposed.
Keywords: montmorillonite, intercalation compounds, potentiometric sensor, clay modified electrode
References
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Udomphan, K., Atchana, Wongchaisuwat, A., & Meesuk, L. (2011). CdS-intercalated bentonite: A novel sulfide ion selective electrode. Applied Mechanics and Materials, 110-116, 472-477. https://doi.org/10. 4028/www.scientific.net/AMM.110-116.472
Udomphan, K., Wongchaisuwat, A., & Meesuk, L. (2014). CdS -bentonite sulfide ion sensor: pH effect and selectivity. Advanced Materials Research, 936, 136-139. https://doi.org/10.4028/www. scientific.net/AMR.936. 136)
Mallakpour, S., & Dinari, M. (2012). Biomodification of Cloisite Na+ with L-methionine amino Acid and preparation of poly(vinyl alcohol)/organoclay nanocomposite films. Journal of Applied Polymer Science, 124, 4,322-4330. https://doi.org/10.1002/app.35540
Mallakpour, S., & Barati, A. (2012). Application of modified Cloisite Na+ with L-phenylalanine for the preparation of new poly (vinyl alcohol)/organo clay bionanocomposite films. Polymer Plastic Technology and Engineering, 51(3), 321-327. https://doi.org/10.1080/03602559.2011. 639335
Ip, K. M., Wang, C. R., Li, Q., & Hark, S. K. (2004). Excitons and surface luminescence of CdS nanoribbons. Applied Physics Letters, 84(5), 795-797. https://doi.org/10.1063/1.1644625
Wei Guicun Li, F., & Zhang, Z. (2005). Synthesis of high quality CdS nanorods by solvothermal process and their photoluminescence. Journal of Nanoparticle Research, 7, 685-689. https://doi.org/ 10. 1007 /s11051-005-7521-7
Li, G., Jiang, L., Peng, H., & Zhang, B. (2008). Self-assembled cadmium sulfide microspheres from nanorods and their optical properties. Materials Letts, 62, 1,881-1,883. https://doi.org/10.1016/j.matlet. 2007.10.029
Dumbrava, A., Badea, C., Prodan, G., & Ciupina, V. (2010). Synthesis and characterization of cadmium sulfide obtained at room temperature. Chacogenide Letters, 7(2), 111-118. https://doi.org/10. 1515/htmp-2015-0143
Kochubey, V. I., Kochubey, D.I., Konyukhova, Y.G., Zabenkov, I.V., Tatarinov, S.I., & Volkova, E. K. (2010). Optical characteristics of cadmium sulfide nanoparticles synthesized in polyethylene matrix and ortho-xylene solution. Optics and Spectroscopy, 109(2), 154-161. https://doi.org/10.1134 /S003040 0X10080023
Sankar, M., Jothibas, M., Muthuvel, A., & Arun Kumar, B. (2020) “Structural, optical, electrical and photocatalytic degradation properties of cadmium sulfide nanoparticles by sol gel method” Asian Journal of Chemistry, 32, 2,347–2,355. https://doi.org/10.14233/ajchem.2020.22769
Khaorapapong, N., Ontam, A., & Okawa, M. (2008). Solid-state intercalation and in situ formation of cadmium sulfide in the interlayer space of montmorillonite. Journal of Physics Chemistry and Solids, 69, 1,107–1,111. https://doi.org/10.1016/j.jpcs.2007.10.101
Khaorapapong, N., Ontam, A., & Okawa, M. (2010). Formation of ZnS and CdS in the interlayer spaces of montmorillonite. Applied Clay Science, 50, 19-24. https://doi.org/10.1016/j.clay.2010.06.013
Seleci, M., Ag, D., Evrim Yalcinkaya, E., Odaci Demirkol, D., Guler, C., & Timur, S. (2012) Amine-intercalated montmorillonite matrices for enzyme immobilization and biosensing applications. RSC Advances, 2, 2,112-2,118. https://doi.org/10.1039/C2RA01225A
Loudiki, A., Boumya, W., Hammani, H., Nasrellah, H., El Bouabi, Y., Zeroual, M., Farahi, A., Lahrich, S., Hnini, K., Achak, M., Bakasse, M., & El Mhammedi, M.A. (2016). Ibuprofen analysis in blood samples by palladium particles-impregnated sodium montmorillonite electrodes: Validation using high performance liquid chromatography. Materials Science and Engineering C, 69, 616-624. https://doi.org/10.1016/j. msec.2016.07.024
Barros, A., Jose Leopoldo Constantino, C., Cristino da Cruz, N., Cristino da Cruz, N. Roberto Rebeiro Bortoleto, J., & Ferreira, M. (2017). High performance of electrochemical sensors based on LbL films of gold nano particles polyaniline and sodium montmorillonite clay mineral for simultaneous detection of metal ions. Electrochimica Acta, 235, 700-708. http://dx.doi.org/10.1016/j.electacta.2017.03.135
Sajid, M. (2018). Bentonite-modified electrochemical sensors: a brief overview of features and applications. Ionics, 24, 19-32. https://doi.org/10.1007/s11581-017-2201-z
Lucena, N. C., Miyazaki, C. M., Shimizu, F. M., Constantino, C. J. L., & Ferreira, M. (2018). Layer-by-Layer composite film of nickel phthalocyanine and montmorillonite clay for synergistic effect on electrochemical detection dopamine. Applied Surface Science, 436, 957-966. https://doi.org/ 10.1016/j.apsusc.2017.12.117)
Udomphan, K., Wongchaisuwat, A., & Meesuk, L. (2010). CdS-intercalated bentonite/carbon composite as electrode for sulfide ion. Materials Science Forum, 663-665, 690-693. https://doi.org/10.4028/ www.scientific.net/MSF.663-665.690
Udomphan, K., Atchana, Wongchaisuwat, A., & Meesuk, L. (2011). CdS-intercalated bentonite: A novel sulfide ion selective electrode. Applied Mechanics and Materials, 110-116, 472-477. https://doi.org/10. 4028/www.scientific.net/AMM.110-116.472
Udomphan, K., Wongchaisuwat, A., & Meesuk, L. (2014). CdS -bentonite sulfide ion sensor: pH effect and selectivity. Advanced Materials Research, 936, 136-139. https://doi.org/10.4028/www. scientific.net/AMR.936. 136)
Mallakpour, S., & Dinari, M. (2012). Biomodification of Cloisite Na+ with L-methionine amino Acid and preparation of poly(vinyl alcohol)/organoclay nanocomposite films. Journal of Applied Polymer Science, 124, 4,322-4330. https://doi.org/10.1002/app.35540
Mallakpour, S., & Barati, A. (2012). Application of modified Cloisite Na+ with L-phenylalanine for the preparation of new poly (vinyl alcohol)/organo clay bionanocomposite films. Polymer Plastic Technology and Engineering, 51(3), 321-327. https://doi.org/10.1080/03602559.2011. 639335
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Research Articles
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How to Cite
UDOMPHAN, Kemawadee; WONGCHAISUWAT, Atchana; MEESUK, Ladda.
Preparation and Characterization of CdS Intercalated Montmorillonite for Potentiometric Sensor Fabrication.
Naresuan University Journal: Science and Technology (NUJST), [S.l.], v. 30, n. 3, p. 31-43, oct. 2021.
ISSN 2539-553X.
Available at: <https://www.journal.nu.ac.th/NUJST/article/view/Vol-30-No-3-2022-31-43>. Date accessed: 26 apr. 2024.
doi: https://doi.org/10.14456/nujst.2022.24.