An Investigation of Phenol Adsorption from Aqueous Solution Using Solid Adsorbents
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Published
Oct 1, 2019
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Abstract
This study reports on removal of phenol on various solid adsorbents namely, activated carbon (AC), zeolite LTL in 2 forms, K-LTL and H-LTL. This work was performed by batch adsorption techniques. The effect of adsorbent, pH and temperature were determined to find out the optimal condition. The amounts of adsorbed phenol were interpreted using Langmuir and Freundlich. K-LTL zeolite was found to be most effective for the removal of phenol than H-LTL and AC. The optimum conditions for maximum adsorption were K-LTL being used as an adsorbent, at pH 4. Moreover, it was found that the adsorption was enhanced with increasing temperature. This results showed that the K-LTL zeolite exhibit a better an adsorbent for the removal of phenol from aqueous solutions. Furthermore, thermodynamic parameters including Gibbs free energy (ΔG°), enthalpy (ΔH°) and entropy (ΔS°) were also determined. The results indicating the adsorption is spontaneous and endothermic process.
Keywords: Zeolite LTL, Activated carbon, Phenol, Adsorption isotherm
References
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El-Aassar, M. R., El-Kady, M. F., Hassan, H. S., & Al-Deyab, S. S. (2016). Synthesis and characterization of surface modified electrospun poly (acrylonitrile-co-styrene) nanofibers for dye decolorization. Journal of the Taiwan Institute of Chemical Engineers, 58, 274-282.
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Yousef, R. I., & El-Eswed, B. (2009). The effect of pH on the adsorption of phenol and chlorophenols onto natural zeolite. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 334, 92-99.
Cheng, W. P., Gao, W., Cui, X., Ma, J. H., & Li, R. F. (2016). Phenol adsorption equilibrium and kinetics on zeolite X/activated carbon composite. Journal of the Taiwan Institute of Chemical Engineers, 62, 192-198.
Dabrowski, A., Podkościelny, P., Hubicki, Z., & Barczak, M. (2005). Adsorption of phenolic compounds by activated carbon—a critical review. Chemosphere, 58, 1049-1070.
Damjanovic´, L., Rakic´, V., Rac, V., Stošic´, D., & Auroux, A. (2010). The investigation of phenol removal from aqueous solutions by zeolites as solid adsorbents. Journal of Hazardous Materials, 184, 477-484.
El-Aassar, M. R., El-Kady, M. F., Hassan, H. S., & Al-Deyab, S. S. (2016). Synthesis and characterization of surface modified electrospun poly (acrylonitrile-co-styrene) nanofibers for dye decolorization. Journal of the Taiwan Institute of Chemical Engineers, 58, 274-282.
Elkady, M. F., Shokry Hassan, H., Amer, W. A., Salama, E., Algarni, H., & Shaaban, E. R. (2017). Novel Magnetic Zinc Oxide Nanotubes for Phenol Adsorption: Mechanism Modeling. Materials, 10, 1355-1370.
Elkady, M. F., Shokry Hassan, H., & El-sayed, E. M. (2015). Basic Violet Decolourization Using Alginate Immobilized Nanozirconium Tungestovanadate Matrix as Cation Exchanger. Journal of Chemistry, 2015, 10. Retrieved From http://dx.doi.org/10.1155/2015/385741
El-Naas, M. H., Al-Zuhair, S., & Alhaija, M. A. (2010). Removal of phenol from petroleum refinery wastewater through adsorption on date-pit activated carbon. Chemical Engineering Journal, 162, 997-1005.
Fungaro, D., Yamaura, M., & Carvalho, T. (2011). Adsorption of anionic dyes from aqueous solution on O zeolite from fly ash-iron oxide magnetic nanocomposite. International Journal of Molecular Sciences, 2, 305-316.
Girish, C. R., & Murty, V. R. (2012). Adsorption of phenol from wastewater using locally available adsorbents. Journal of Environmental Research and Development A, 6(3A), 763-772.
Girish, C. R., & Murty, V. R. (2012). Review of various treatment methods for the abatement of phenolic compounds from wastewater. Journal of Environmental Science and Engineering, 54(2), 306-316.
Girish, C. R., & Murty, V. R. (2014). Adsorption of Phenol from Aqueous Solution Using Lantana camara, Forest Waste: Kinetics, Isotherm, and Thermodynamic Studies. International Scholarly Research Notices, 2014, 16.
Girods, P., Dufour, A., Fierro, V., Rogaume, Y., Rogaume, C., Zoulalian, A., & Celzard, A. (2009). Activated carbons prepared from wood particleboard wastes: Characterisation and phenol adsorption capacities. Journal of Hazardous Materials, 166, 491-501.
Insuwan, W., & Rangsriwatananon, K. (2012). Morphology-controlled synthesis of zeolite L and physicochemical properties. Engineering journal, 16, 1-12.
Insuwan, W., & Rangsriwatananon, K. (2014). Evaluation of adsorption of cationic dyes on H-LTL and K-LTL zeolite. Journal of Porous Materials, 21, 345-354.
Lorenc-Grabowska, E. (2016). Effect of micropore size distribution on phenol adsorption on steam activated carbons. Adsorption, 22(4-6), 599-607.
Nevskaia, D. M., Santianes, A., Muñoz, V., & Guerrero-Ruíz, A. (1999). Interaction of aqueous solutions of phenol with commercial activated carbons: an adsorption and kinetic study. Carbon, 37, 1065-1074.
Okolo, B., Park, C., & Keane, M. A. (2000). Interaction of Phenol and Chlorophenols with Activated Carbon and Synthetic Zeolites in Aqueous Media. Journal of Colloid and Interface Science, 226, 308-317.
Rodríguez Arana, J. M. R., & Mazzoco, R. R. (2010). Adsorption studies of methylene blue and phenol onto black stone cherries prepared by chemical activation. Journal of Hazardous Materials, 180, 656-661.
Tan, I. A. W., Ahmad, A. L., & Hameed, B. H. (2008). Enhancement of basic dye adsorption uptake from aqueous solutions using chemically modified oil palm shell activated carbon. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 318, 88-96.
Uddin, M.T., Islam, M., & Abedin, M. (2007). Adsorption of Phenol from Aqueous Solution by Water Hyacinth Ash. Journal of Engineering and Applied Sciences, 2, 11-17.
Yousef, R. I., & El-Eswed, B. (2009). The effect of pH on the adsorption of phenol and chlorophenols onto natural zeolite. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 334, 92-99.
Section
Research Articles
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How to Cite
INSUWAN, Wilaiporn; SAOSAI, Nantana.
An Investigation of Phenol Adsorption from Aqueous Solution Using Solid Adsorbents.
Naresuan University Journal: Science and Technology (NUJST), [S.l.], v. 27, n. 4, p. 1-9, oct. 2019.
ISSN 2539-553X.
Available at: <https://www.journal.nu.ac.th/NUJST/article/view/Vol-27-No-4-2019-1-9>. Date accessed: 18 apr. 2024.
doi: https://doi.org/10.14456/nujst.2019.31.