Removal of Heavy Metal from Synthetic WastewaterUsing Calcined Golden Apple Snail Shells


Chatyapha Ketwong Somsuk Trisupakitti Chompoo Nausri Watchara Senajuk


     Westudied the removal of heavy metals from synthetic waste water samples by using Golden Apple Snail shells,calcined at 1050OC: they were able to removeup to 30% of copper(II) ions, 88% of cadmium(II) ions and 56% of lead(II) ions. The best performance was at pH 6. Metal removal followed a stable pseudo-second order reaction equation with parameters, k2 and qe, with k2 values for Cu2+0.00377, Cd2+ 0.00278 and Pb2+ 0.00365 g/mg-min and qe values of  9.65,25.9, 16.8 mg/g and we concluded that the sorption mechanism is primarily absorption into the pores of the sorbent . This adsorbing material had two advantages, that is, lower volume of the Golden Apple Snail Shell and a cost-effective absorbent. If further developed, this could lead to better and effective low cost treatment for polluted waste waters.

Keywords:Golden Apple Snail Shell, Absorption, Cadmium, Copper, Lead, Sorption kinetics


Ajay, K.A., &Mahendra, S.K. (2015). Kinetics study on the adsorption of Ni2+ ions onto fly ash. Journal of Chemical Technology and Metallurgy, 50(5), 601-605.
Ali, I., Asim, M., & Khan, T.A. (2012). Low cost adsorbents for the removal of organic pollutants from wastewater. Journal of Environmental Management, 113, 170-183.
Babel S., &Kurniawan, T.A. (2003). Low-cost adsorbents for heavey metals uptake from contaminated water. Journal of Hazardous Materials, 97(1-3), 219-243.
Barakat, M.A., Chen, Y.T., & Huang, C.P. (2004). Removal of toxic cyanide and Cu(II) ions from water by illuminated TiO2 catalyst. Applied Catalysis B: Environmental, 53(1), 13-20.
Barakat, M.A. (2011). New trends in removing heavey metals from industrial wastewater. Arabian Journal of Chemistrys, 4, 361-377.
Boonyuen, M., Malaithong, A., Prokaew, B., Cherdhirunkorn,B., &Chuasantia, I. (2015). Decomposition study of calcium carbonate. Thai Journal of Science and Technology, 4(2), 115-122.
Chanyaporn, P. (2002). Removal of lead from waste water by cockle shell and mussel shell. Chulalongkorn University, Bangkok, Thailand.
Jacob, D.E., Soldati, A.L., Wirth, R., Huth, J., Wehrmeister, U., &Hofmeister, W. (2008). Nanostructure, composition and mechanisms of bivalve shell growth. GeochimicaetCosmochimicaActa, 72(22), 5401-5415.
Jung, T.P., Makeig, S., Marissa, W., Townsend, J., Courchesene, E.,&Sejnowski, T.J. (2000). Removal of eye activity artifacts from visual event-related potentials in normal and clinical subjects. Clinical Neurophysiology, 111, 1745-1758.
Hale, G., Drumm, A., Harrison, P.,& Phillips, J. (1994). Repeated cleaning of protein A affinity column with sodium hydroxide. Journal of Immunological Methods, 171(1), 15-21.
Kajitvichyanukula, P., Ananpattarachaia, J., &Pongpom, S. (2005). Sol-gel preparation and properties study of TiO2 thin film for photocatalytic reduction of chromium(VI) in photocatalysis process. Science and Technology of Advanced Materials, 6(3-4), 352-358.
Kaplan, D.L. (1998). Mollusk shell structures: Novel design strategies for synthetic materials.Current Opinion in Solid State Material Science, 3(3), 232-236.
Kurniawan, T.A., Chan, G.Y.S., Lo, W.H., & Babel, S. (2006). Physico-chemical treatment techniques for wastewater laden with heavy metals. Chemical Engineering Journal, 118(1-2), 83-98.
Mohammadi, T., Mohebb, A., Sadrzadeh, M., &Razmi, A. (2005). Modeling of metal ion removal from wastewater by electrodialysis. Separation and Purification Technology,41(1), 73-82.
Mustakimah, M., Suzana, Y.,&Saikat, M. (2012). Decomposition study of calcium carbonate in cockle shell. Journal of Engineering Science and Technology, 7, 1-10.
Nisarat, J. (2013). Removal of Cu Mn and Zn by adsorption process with mollusk shell. Burapha University, Chonburi, Thailand.
Orapin, T. (2007). Treatment of zinc and copper in metal manufacture wastewater by tea residue. Kasetsart University, Bangkok, Thailand.
Panumas, P., Nakorn, I., &Chanjam, D. (2008). Biosorption of copper ions from aqueous solution by grape waste. Research and Development Journal:LoeiRajabhat University, 3(3), 104-118.
Pattama, S. (2000). Effect of leaf extracts from eupatorium Odoratum L. on detoxification enzymes levels in golden apple snail. Kasetsart University, Bangkok, Thailand.
Saowapa, W. (2016). Phosphate removal in wastewater by adsorption on calcium carbonate and calcium oxide from eggshell. The Journal of King Mongkut’s University of Technology North Bangkok, 26(3), 476-486.
Tabtong, C.,&Juijuljerm, S. (2000). Adsorption of lead ions from synthetic waste water using oyster shell. Journal Environmental Research, 31(1), 45-53.
Wang, C., Sheng, Y., Bala, H., Zhao, X., Zhao, J., Ma, X.,& Wang, Z. (2007). A novel aqueous-phase route to synthesize hydrophobic CaCO3 particles in situ. Materials Science Engineering :C, 27(1), 42-45.
Yijun, Z., Shengyong, L., &Huimin, W. (2014). Experiment study on the decomposition properties of snail shell. Biotechnology, 9(8), 303-307.
Yupadee, S. (2004). Removal of Cadmium(II) and Lead(II) ions from wastewater by Tamarind and Pomegranate shell. Journal of Science and Technology, 22(2), 184-201.

Research Articles


How to Cite
KETWONG, Chatyapha et al. Removal of Heavy Metal from Synthetic WastewaterUsing Calcined Golden Apple Snail Shells. Naresuan University Journal: Science and Technology (NUJST), [S.l.], v. 26, n. 4, p. 61-70, nov. 2018. ISSN 2539-553X. Available at: <>. Date accessed: 15 apr. 2024. doi: