Adsorption Efficiency of Fe(III) from Solution by Zeolite Y Synthesized from Rice Husk
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Published
Sep 24, 2018
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Abstract
The purposes of this work were to prepare zeolite Y in sodium form (NaY) by using silica from rice husk, and to test the adsorption efficiency of the prepared NaY. The NaY was characterized by x-ray diffraction (XRD) and Brunauer, Emmett and Teller (BET) to confirm their structures and properties including isotherm adsorption and surface area. In addition, the adsorption efficiency of the NaY was tested in Fe(III) solution. The adsorption characteristics, contact time, initial concentration of iron solution, pH, and amount of adsorbent on the NaY, were studied. The time taken to reach equilibrium was 30 min. The amount of iron solution adsorbed increased as the pH increased, and the optimum values were pH 4.0-6.0. The adsorption capacity of the iron species in a solution at 30 °C was 57.80 mg/g, at 40 °C, 90.91 mg/g, and at 50 °C, 60.61 mg/g. The isotherms and isotherm constants were depicted from the results of the Langmuir and Freundlich adsorption. Adsorption isotherm data of the Fe(III) solution, when tested at 30 °C, could be well explained by the Langmuir model but that of Fe (III) tested at 40 °C and 50 °C were more related to the Freundlich model. The positive enthalpy (ΔH°) and the negative Gibbs free energy (ΔG°) suggested that the process of adsorption of the iron solution on the NaY was endothermic and spontaneous. The study of the kinetic adsorption model correlated with the pseudo-second order.
Keywords: zeolite, adsorption, iron, rice husk
References
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Real, C., Alcala, M. D., & Criado, J. M. (1996) Preparation of Silica from Rice Husks. Journal of the American Ceramic Society, 79(8), 2012-2016.
Ren, H., Gao, Z., Wu, D., Jiang, J., Sun, Y., & Luo, C. (2016). Efficient Pb(II) removal using sodium alginate-carboxymethyl cellulose gel beads: Preparation, characterization, and adsorption mechanism. Carbohydrate Polymers, 137, 402–409.
Seliem, M. K., & Komarneni, S. (2016) Equilibrium and kinetic studies for adsorption of iron from aqueous solution by synthetic Na-A zeolites: Statistical modeling and optimization. Microporous and Mesoporous Materials, 228, 266-274.
Sharififard, H., Pepe, F., Soleimani, M., Aprea, P., & Caputo, D. (2016) Iron-activated carbon nanocomposite: synthesis, characterization and application for lead removal from aqueous solution. RSC Advances, 6, 42845-42853.
Villa, A. L., Caro, C. A., & de Correa, C. M. (2005). Cu- and Fe-ZSM-5 as Catalysts for Phenol Hydroxylation. Journal of Molecular Catalysis A: Chemical, 228(1-2), 233-240.
Wang, L., Zhang, J., Zhao, R., Li, Y., & Zhang, C. (2010). Adsorption of Pb(II) on activated carbonprepared from Polygonumorientale Linn. : Kinetics, isotherms, pH, and ionic strength studies. Bioresource Technology, 101(15), 5808-5814.
Wantala, K., Sthiannopkao, S., Srinameb, B., Grisdanurak, N., & Kim, K. W., (2010). Synthesis and characterization of Fe-MCM-41 from rice husk silica by hydrothermal technique for arsenate adsorption. Environ Geochem Health, 32(4), 261–266.
Wittayakun, J., & Grisdanurak, N., (2004). Catalysis: Fundamentals and Applications. Bangkok: Thammasat Printing house.
Wittayakun, J., Khemthong, P., & Prayoonpokarach, S., (2008) Synthesis and characterization of zeolite NaY from rice husk silica. Korean Journal of Chemical Engineering, 25(4), 861-864.
Wu, C. H., (2007). Adsorption of reactive dye onto carbon nanotubes: Equilibrium, kinetics and thermodynamics. Journal of Hazardous Materials, 144(1-2), 93–100.
Zhao, W., Luo, Y., Deng, P., & Li, Q., (2001). Synthesis of Fe-MCM-48 and Its Catalytic Performance in Phenol Hydroxylation. Catalysis Letters, 73(2-4), 199-202.
Brook, M. A., Castle, L., Smith, J. R. L., Higgins, R., & Morris, K. P. (1982). Aromatic hydroxylation, part 7, oxidation of some benzenoid compounds by iron compounds and hydrogen peroxide with the aromatic compound acting as substrate and solvent. Journal of the American Chemical Society, Perkin Transactions 2, 687-692.
Bunmai, K., Osakoo, N., Deekamwong, K., Rongchapo, W., Keawkumay C., Chanlek, N., Prayoonpokarach, S., & Wittayakun, J. (2018). Extraction of silica from cogon grass and utilization for synthesis of zeolite NaY by conventional and microwave-assisted hydrothermal methods. Journal of the Taiwan Institute of Chemical Engineers, 83, 152-158.
Choi, J. S., Yoon, S. S., Jang, S. H., & Ahn, W. S., (2006). Phenol hydroxylation using Fe-MCM-41 catalysts. Catalysis Today, 111(3-4), 280-287.
Deng, R., Hu, Y., Ku, J., Zuo, W., & Yang, Z. (2017). Adsorption of Fe(III) on smithsonite surfaces and implications for flotation. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 533, 308-315.
Faust, S. D., & Aly, O. M. (1987). Adsorption process for water treatment. Butterworths Publishers: Stoneham.
Ginter, D. M., Bell, A. T., & Radke, C. J. (1992). The effects of gel aging on the synthesis of NaY zeolite from colloidal silica. Zeolites. 12(6), 742-749.
Hashemian, S., Hosseini, S. H., Salehifar, H., & Salari, K. (2013). Adsorption of Fe(III) from aqueous solution by Linde Type-A zeolite. American Journal of Analytical Chemistry, 4, 123-126.
He, J., Hong, S., Zhang, L., Gan, F., & Ho, Y.S. (2010). Equilibrium and thermodynamic parameters of adsorption of methylene blue onto rectorite. Fresenius Environmental Bulletin, 19(11a.), 2651-2656.
Johar, N., Ahmad, I., & Dufresne, A. (2012). Extraction, preparation and characterization of cellulose fibres and nanocrystals from rice husk. Industrial Crops and Products, 37(1), 93-99.
Khemtong, P., Prayoonpokarach, S., & Wittayakun, J. (2007). Synthesis and Characterization of Zeolite LSX from Rice Husk Silica. Suranaree Journal Science Technology, 14(4), 367-379.
Kosri, C., Deekamwong, K., Sophiphun, O., Osakoo, N., Chanlek, N., Karin, F., & Wittayakun, J. (2017). Comparison of Fe/HBEA catalysts from incipient wetness impregnation with various loading on phenol hydroxylation. Reaction Kinetics, Mechanisms and Catalysis, 121, 751-761.
Kulawong, J., & Kulawong, S. (2017, 8-11 February). Phenol adsorption on zeolite NaY synthesized from rice husk silica. 12th International workshop for east asian young rheologists, Thailand: Chonburi.
Kulawong, S., Prayoonpokarach, S., Neramittagapong, A., & Wittayakun, J. (2011). Mordenite modification and utilization as supports for iron catalyst in phenol hydroxylation. Journal of Industrial and Engineering Chemistry, 17(2), 346-351.
Mäki-Arvela, P., & Murzin D.Y. (2013) Effect of catalyst synthesis parameters on the metal particle size. Applied Catalysis A: General. 451, 251-281.
Osakoo, N., Pansakdanon, C., Sosa, N., Deekamwong, K., Keawkumay C., Rongchapo, W., … Wittayakun, J. (2017). Characterization and comprehension of zeolite NaY/mesoporous SBA-15 composite as adsorbent for paraquat. Materials Chemistry and Physics, 193(1), 470-476.
Park, J. N., Wang, J., Choi, K. Y., Dong, W. Y., Hong, S. I., & Lee, C. W., (2006). Hydroxylation of Phenol with H2O2 over Fe2+ and/or Co2+ Ion-exchanged NaY Catalyst in the Fixed-bed Flow Reactor. Journal of Molecular Catalysis A: Chemical, 247(1-2), 73-79.
Preethi, M. E. L., Revathi, S., Sivakumar, T., Manikandan, D., Divakar, D., Rupa, A. V., & Palanichami, M. (2008). Phenol hydroxylation using Fe/Al-MCM-41 catalysts. Catalysis Letters, 120(1-2), 56-64.
Rakmae, S., Keawkumay, C., Osakoo, N., Montalbo, K. D., de Leon, R. L., Kidkhunthod, P., … Wittayakun, J. (2016) Realization of active species in potassium catalysts on zeolite NaY prepared by ultrasound-assisted impregnation with acetate buffer and improved performance in transesterification of palm oil. Fuel, 184, 512-517.
Real, C., Alcala, M. D., & Criado, J. M. (1996) Preparation of Silica from Rice Husks. Journal of the American Ceramic Society, 79(8), 2012-2016.
Ren, H., Gao, Z., Wu, D., Jiang, J., Sun, Y., & Luo, C. (2016). Efficient Pb(II) removal using sodium alginate-carboxymethyl cellulose gel beads: Preparation, characterization, and adsorption mechanism. Carbohydrate Polymers, 137, 402–409.
Seliem, M. K., & Komarneni, S. (2016) Equilibrium and kinetic studies for adsorption of iron from aqueous solution by synthetic Na-A zeolites: Statistical modeling and optimization. Microporous and Mesoporous Materials, 228, 266-274.
Sharififard, H., Pepe, F., Soleimani, M., Aprea, P., & Caputo, D. (2016) Iron-activated carbon nanocomposite: synthesis, characterization and application for lead removal from aqueous solution. RSC Advances, 6, 42845-42853.
Villa, A. L., Caro, C. A., & de Correa, C. M. (2005). Cu- and Fe-ZSM-5 as Catalysts for Phenol Hydroxylation. Journal of Molecular Catalysis A: Chemical, 228(1-2), 233-240.
Wang, L., Zhang, J., Zhao, R., Li, Y., & Zhang, C. (2010). Adsorption of Pb(II) on activated carbonprepared from Polygonumorientale Linn. : Kinetics, isotherms, pH, and ionic strength studies. Bioresource Technology, 101(15), 5808-5814.
Wantala, K., Sthiannopkao, S., Srinameb, B., Grisdanurak, N., & Kim, K. W., (2010). Synthesis and characterization of Fe-MCM-41 from rice husk silica by hydrothermal technique for arsenate adsorption. Environ Geochem Health, 32(4), 261–266.
Wittayakun, J., & Grisdanurak, N., (2004). Catalysis: Fundamentals and Applications. Bangkok: Thammasat Printing house.
Wittayakun, J., Khemthong, P., & Prayoonpokarach, S., (2008) Synthesis and characterization of zeolite NaY from rice husk silica. Korean Journal of Chemical Engineering, 25(4), 861-864.
Wu, C. H., (2007). Adsorption of reactive dye onto carbon nanotubes: Equilibrium, kinetics and thermodynamics. Journal of Hazardous Materials, 144(1-2), 93–100.
Zhao, W., Luo, Y., Deng, P., & Li, Q., (2001). Synthesis of Fe-MCM-48 and Its Catalytic Performance in Phenol Hydroxylation. Catalysis Letters, 73(2-4), 199-202.
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How to Cite
KULAWONG, Sittichai; KULAWONG, Jittima.
Adsorption Efficiency of Fe(III) from Solution by Zeolite Y Synthesized from Rice Husk.
Naresuan University Journal: Science and Technology (NUJST), [S.l.], v. 26, n. 3, p. 144-156, sep. 2018.
ISSN 2539-553X.
Available at: <https://www.journal.nu.ac.th/NUJST/article/view/Vol-26-No-3-2018-114-156>. Date accessed: 19 apr. 2024.
doi: https://doi.org/10.14456/nujst.2018.2.